Explosive silver
How to make an explosion using silver
Explosive silver in an explosive new video!
Safety precautions
Do not try this at home. Only under professional supervision.
Reagents and equipment
- calcium carbide;
- 50mL Tollens’ reagent;
- water;
- conical flasks;
- cork with gas pipe;
- funnel;
- filter paper;
- burner.
Step-by-step instructions
Add a small piece of calcium carbide to a conical flask with 50mL of water, and close it using a cork with a gas outlet tube. Immerse the free end of the gas outlet tube in 50mL of Tollens’ reagent. Wait for the reaction to die down. A loose, greyish-white precipitate will form in the second flask. Filter it through a funnel with filter paper and rinse with water. Pat the precipitate dry with filter paper and set a small amount on fire. And boom!
Process description
The reaction between calcium carbide and water produces acetylene gas and calcium hydroxide:
CaC₂+2H₂O→Ca(OH)₂+C₂H₂↑
Passing acetylene gas through a solution of Tollens’ reagent (ammonia silver hydroxide solution) yields a friable grey-white precipitate of silver acetylide:
C₂H₂+2[Ag(NH3)₂]OH→Ag₂C₂↓+4NH₃↑+2H₂O
Silver acetylide is an extremely unstable explosive. The fewer impurities it contains, the more dangerous it is. Silver acetylide can explode when heated and mechanically stressed.
Ag₂C₂(solid)→2Ag(solid)+2C(solid)