Capture a mystical sulfur fog in a Petri dish!
- Put on protective gloves and eyewear.
- Conduct the experiment on the plastic tray.
- Observe safety precautions when working with boiling water.
- Do not allow chemicals to come into contact with the eyes or mouth.
- Keep young children, animals and those not wearing eye protection away from the experimental area.
- Store this experimental set out of reach of children under 12 years of age.
- Clean all equipment after use.
- Make sure that all containers are fully closed and properly stored after use.
- Ensure that all empty containers are disposed of properly.
- Do not use any equipment which has not been supplied with the set or recommended in the instructions for use.
- Do not replace foodstuffs in original container. Dispose of immediately.
- In case of eye contact: Wash out eye with plenty of water, holding eye open if necessary. Seek immediate medical advice.
- If swallowed: Wash out mouth with water, drink some fresh water. Do not induce vomiting. Seek immediate medical advice.
- In case of inhalation: Remove person to fresh air.
- In case of skin contact and burns: Wash affected area with plenty of water for at least 10 minutes.
- In case of doubt, seek medical advice without delay. Take the chemical and its container with you.
- In case of injury always seek medical advice.
- The incorrect use of chemicals can cause injury and damage to health. Only carry out those experiments which are listed in the instructions.
- This experimental set is for use only by children over 12 years.
- Because children’s abilities vary so much, even within age groups, supervising adults should exercise discretion as to which experiments are suitable and safe for them. The instructions should enable supervisors to assess any experiment to establish its suitability for a particular child.
- The supervising adult should discuss the warnings and safety information with the child or children before commencing the experiments. Particular attention should be paid to the safe handling of acids, alkalis and flammable liquids.
- The area surrounding the experiment should be kept clear of any obstructions and away from the storage of food. It should be well lit and ventilated and close to a water supply. A solid table with a heat resistant top should be provided
- Substances in non-reclosable packaging should be used up (completely) during the course of one experiment, i.e. after opening the package.
FAQ and troubleshooting
It’s fine! This won’t affect the experiment.
Yes, everything is alright. During the reaction, sulfur dioxide gas is released in the form of bubbles – its slight odor can be felt during the experiment. The bubbles pop so noticeably because they burst in a thin layer of liquid, which makes it much louder.
You can try preparing the concentrated solution first. And if you are a very curious scientist, you can prepare the solutions separately and time how long it takes the sulfur fog to form in each of them!
To get a better look at the reaction, you’ll need two Petri dishes against a black background.
The first ingredient is NaHSO4. The part you're interested in is the "H" in the middle: it stands for an H+ ion.
The second ingredient is Na2S2O3. Here, the important part is "S2O3". It stands for an S2O32- ion. The only difference between the dishes is the amount of Na2S2O3 you add.
Now watch what happens!
The precipitate is formed at different speeds in different Petri dishes
Dispose of the reagents and solid waste together with household garbage. Pour solutions down the sink and wash with an excess of water.
In a nutshell, two H+ ions stumble upon S2O32- and rip away one of its oxygens O and two electrons "2-", forming water H2O . The remaining part ultimately breaks down into SO2 molecules , which you can observe as tiny bubbles, and pure sulfur S , which is the whitish-yellow precipitate.
As you can see, the reaction happens in both dishes, but a lot faster in the dish with more Na2S2O3. That's because the more S2O32- ions there are, the more often they run into H+ ions .
But can you speed the reaction up without overcrowding the solution with reagents? Think about it. Instead of making S2O32- ions more abundant, you can make all the particles run around faster! That’s actually easier than it might seem, because it's just a fancy way of saying "heat the solution up." You can try it for yourself: repeat the experiment, but instead of adding more Na2S2O3 to one dish, use hot water to prepare the solutions.
What else can speed up a reaction?
For two substances to react, their particles (molecules, atoms, or ions) must run into each other. The more often these particles collide, the higher the reaction rate. As you already know, there are several ways to speed up a reaction.
First, you can add more reagents – the more particles a solution contains, the more often they bump into each other, like people in a crowd.
Alternatively, you can make the particles move faster, which, practically speaking, means "heat the solution up." In the same period of time, fast-moving particles will collide with each other more frequently than slow-moving ones.
This next method is not feasible at home, as it requires special equipment. By increasing the pressure, i.e. compressing the liquid, we can make the particles huddle closer together, and therefore cause them to collide more often.
Finally, special substances called catalysts can be added to a solution to increase the reaction rate, sometimes even by a factor of multiple billion! These chemical “assistants” help substances react with each other, but aren't used up during a reaction. Each reaction can only be sped up by specific catalysts suitable for it.